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dc.contributor.authorMoradi, Mina
dc.contributor.authorTulli, Ludovico
dc.contributor.authorNowakowski, Jan
dc.contributor.authorBaljozovic, Milos
dc.contributor.authorJung, Thomas A
dc.contributor.authorShahgaldian, Patrick
dc.date.accessioned2018-01-23T08:45:02Z
dc.date.available2018-01-23T08:45:02Z
dc.date.issued2017-11-13
dc.identifier.doi10.1002/anie.201703825
dc.identifier.urihttp://hdl.handle.net/11654/25899
dc.description.abstractA flexible and versatile method to fabricate two-dimensional metal–organic coordination networks (MOCNs) by bottom-up self-assembly is described. 2D crystalline layers were formed at the air–water interface, coordinated by ions from the liquid phase, and transferred onto a solid substrate with their crystallinity preserved. By using an inherently three-dimensional amphiphile, namely 25,26,27,28-tetrapropoxycalix[4]arene-5,11,17,23-tetracarboxylic acid, and a copper metal node, large and monocrystalline dendritic MOCN domains were formed. The method described allows for the fabrication of monolayers of tunable crystallinity on liquid and solid substrates. It can be applied to a large range of differently functionalized organic building blocks, also beyond macrocycles, which can be interconnected by diverse metal nodes.
dc.description.urihttp://onlinelibrary.wiley.com/doi/10.1002/anie.201703825/full
dc.language.isoen_US
dc.relation.ispartofAngewandte Chemie, International Edition
dc.accessRightsAnonymous
dc.subjecttwo-dimensional
dc.subjectcalix[4]arene-based metal-organic
dc.subjecttunable crystallinity
dc.titleTwo-dimensional calix[4]arene-based metal-organic coordination networks of tunable crystallinity
dc.type01 - Zeitschriftenartikel, Journalartikel oder Magazin
dc.volume56
dc.issue46
dc.audienceScience
fhnw.publicationStatePublished
fhnw.ReviewTypeAnonymous ex ante peer review of a complete publication
fhnw.InventedHereYes
fhnw.PublishedSwitzerlandNo
fhnw.pagination14395–14399
fhnw.IsStudentsWorkno
fhnw.publicationOnlineJa


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